Cliff’s Notes: Nitrates Quick Reference

Clifton L. Willms, Ph.D., P.A.S.

Cattle Nutritionist

The nitrate content of feeds can be expressed as nitrate (NO3), nitrate nitrogen (NO3-N), or potassium nitrate (KNO3) depending on the preferred analytical method of the lab that one uses. Each method is equally valid. The important thing is to know how to properly interpret the values. Note the method of expression from your laboratory analysis, then look under the appropriate column to determine the level of risk.

NO3

NO3 -N

KNO3

 

 

Nitrate

 

Nitrate-Nitrogen

 

Potassium Nitrate

 

Comments

ß ----------------- ppm, DM Basis ----------------à

 

0 – 4,400

0 – 1,000

0 – 7,200

Safe

4,400 – 6,600

1,000 – 1,500

7,200 – 10,800

Safe to non-pregnant animals

Limit to 50% in pregnant animals

6,600 – 8,800

1,500 – 2,000

10,800 – 14,400

Limit to ½ of the ration (DM basis)

Do not feed to pregnant animals

   

14,400 – 25,200

Limit to 1/3 of ration (DM basis)

8,800 – 17,600

2,000 – 4,000

25,200 – 28,800

Limit to ¼ of the ration (DM basis)

> 17,600

> 4,000

> 28,800

Do not feed

What causes high nitrates in plants?

Anything that disrupts the normal growth of a plant can set the stage for excessive levels of nitrates (e.g. drought, hail, frost damage). While the plant is growing, it is in the process of transporting nitrogen from the soil (in the form of nitrates) and synthesizing it into plant protein. When that growth process is slowed or interrupted, the metabolic machinery that converts nitrates to protein does not work efficiently and consequently nitrates accumulate, especially in the lower portion of the stalk. For the first few days after a rain, nitrate levels can be excessive since the plant takes up additional nutrients, yet there has not been adequate time to convert nitrates to plant protein. Extended cloudy weather or dense plant populations that create shading of the leaves can also cause toxic levels of nitrates in plants.

Management practices to prevent the occurrence of nitrate toxicity:

  1. Forage test to know the levels in the forages that you are going to feed.
  2. Put the forage crop up as silage rather than green chop or hay. During the fermentation process, the bacterial action will convert much of the nitrate to protein. Nitrate content can be reduced by about 50% after the fermentation process is complete.
  3. Note: Some of the nitrates are lost in the conversion to nitrogen oxide gasses. These are often visible as yellow-red fumes. These gasses are toxic to man and animals and are heavier than air. If upright silos are used, extreme caution must be used to aerate the silo before one enters the silo and to prevent build-up in closed barns to which silos are attached.

  4. Cut the silage or forage extra high. The highest concentration of nitrates is in the lower part of the stalk. By raising the cutter bar an extra 6" to 12", the nitrate content can be reduced in the total crop harvested.
  5. Blend the high nitrate forage with other feeds so that it is only a portion of the ration. Using a good mixer wagon is helpful to get a good blend with other feedstuffs. This dilutes the overall nitrate concentration of the diet and insures that one animal doesn’t get a disproportionate amount of the toxic forage.
  6. Gradually introduce livestock to the feed that has high nitrates over a period of time rather than abruptly feeding it to animals. Also split the feeding up over several meals during the day. Small amounts spread out over time prevents overloading the system. Also, the rumen microbial population can adapt such that microbial species more efficient at metabolizing nitrates begin to flourish. There is still, however, a limit to the amount of nitrates that can be tolerated in the diet.

Forage crops commonly affected:

Forage crops and the form in which they are fed differ in their risk level pertaining to nitrate toxicity.

Forage crop

Highest Risk

Form fed

Sorghums, sudan hybrids, corn

|

|

|

V

Green chop

Oats and cereal crops

Pasture

Grasses

Hay

Legumes

Silage

 

Lowest Risk

 

Sorghums, sudan hybrids, and corn put up as forages can have high nitrate levels.

Oat hay and straw tends to have high nitrates more so than wheat, barley, or rye hays and straws. Also, certain weeds (wild sunflowers, pigeon grass, pig weed, kochia, and thistle) are known to accumulate nitrates.

The grain of oats, other cereals, corn and sorghums does not contain nitrates in toxic amounts. Native grasses, timothy and bromegrass hays, and alfalfa do not appear to be a concern.

Misconception:

Contrary to popular belief, feeding urea does not aggravate nitrate toxicity. Both urea and nitrates are nitrogenous compounds, but they are metabolized differently. Nitrate is rapidly converted to nitrite (NO2) and nitrite is slowly converted to ammonia. It is the build up of nitrite that creates the problem. Nitrite is absorbed into the blood stream and links to hemoglobin and reduces the ability of the blood to carry oxygen. In essence the animal suffocates.

More information:

This article is primarily intended to be a quick reference. For more complete information on nitrates, you can check these web sites:

bulletwww.ansi.okstate.edu/exten/beef/f-2903.pdf Nitrate Toxicity in Livestock
bullet http://www.iowabeefcenter.org/content/newsrel/2001/701/nitrate_toxicity.htm
bullethttp://ohioline.ag.ohio-state.edu/b744/index.html Nitrate in Drinking Water Bulletin 857-96

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